HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitrosobis(2-hydroxypropyl)amine → 2,6-Naphthalenedimethanol, alpha,alpha,alpha',alpha'-tetramethyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitrosobis(2-hydroxypropyl)amine | HCID 40828 | — |
| Reactant | HCID 13781869 | HCID 13781869 | — |
| Product | 2,6-Naphthalenedimethanol, alpha,alpha,alpha',alpha'-tetramethyl- | HCID 185558 | — |
| Product | 2-(6-Propan-2-ylnaphthalen-2-yl)propan-2-ol | HCID 186296 | — |
| Product | Hydroperoxide, 1-methyl-1-[6-(1-methylethyl)-2-naphthalenyl]ethyl | HCID 9816285 | — |
| Product | HCID 13781870 | HCID 13781870 | — |
Reaction Steps
The DIPN conversion was 92.8 mol %, and the yield of 2,6-bis(2-hydroperoxy-2-propyl)naphthalene was 33.4 mol %. In addition, 2-(2-hydroxy-2-propyl)-6-(2-hydroperoxy-2-propyl)-naphthalene, 2,6-bis(2-hydroxy-2-propyl)naphthalene, 2-(2-hydroperoxy-2-propyl)-6-isopropylnaphthalene, and 2-(2-hydroxy-2-propyl)-6-isopropylnaphthalene were produced in yields of 19.1 mol %, 3.3 mol %, 25.2 mol %, and 8.9 mol %, respectively. The conversion of the isopropyl groups was 75.8 mol %.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05196598 |
| Source dataset | uspto-grants-1993_03 |
| ORD ID | ord-b96a6462bde6496982993bcaf0f66a4c |
| Source note | uspto-grants-1993_03 |