HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,4-Dichlorotoluene → 2,4-Dichlorobenzyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,4-Dichlorotoluene | HCID 7254 | — |
| Reactant | Chlorine | HCID 24526 | — |
| Catalyst | Azobisisobutyronitrile | HCID 6547 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 2,4-Dichlorobenzyl chloride | HCID 7212 | — |
Reaction Steps
1 Mol of 2,4-dichloro-methylbenzene and 322 g of carbon tetrachloride are heated to reflux. 0.8 g of azobisisobutyronitrile is added and chlorine gas is introduced in a slight excess. After 0.5 hours, 0.75 mol of product is obtained according to gas-chromatographic analysis.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05198549 |
| Source dataset | uspto-grants-1993_03 |
| ORD ID | ord-ac1a68cb7b464bcb9425953e198cee97 |
| Source note | uspto-grants-1993_03 |