HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,4-Dichlorotoluene → 2,4-Dichlorobenzyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,4-Dichlorotoluene | HCID 7254 | — |
| Reactant | Chlorine | HCID 24526 | — |
| Catalyst | Azobisisobutyronitrile | HCID 6547 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | 2,4-Dichlorobenzyl chloride | HCID 7212 | — |
Reaction Steps
1 Mol of 2,4-dichloro-methylbenzene and 322 g of acetonitrile are heated to reflux. 0.8 g of azobisisobutyronitrile is added and this addition is repeated every half hour. Chlorine gas is simultaneously introduced in a slight excess. 0.75 Mol of product is obtained after 2 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05198549 |
| Source dataset | uspto-grants-1993_03 |
| ORD ID | ord-a6a48178ea2b4f8aad6711db93179c9e |
| Source note | uspto-grants-1993_03 |