Benzoyl Peroxide → 1,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

HRID 1614803Notes

Reaction equation

HRID 1614803 reaction equation
[C:1]1([C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:8][CH3:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[Br:34]N1C(=O)CCC1=O>C(Cl)(Cl)(Cl)Cl>[Br:34][CH2:9][CH:8]=[C:7]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1)[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 2382071,1-Diphenyl-1-propene

Product 1

HCID 123465451,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

A mixture of 1,1-diphenyl-1-propene (17.0 g, 0.10 mol), carbon tetrachloride (100 ml), benzoylperoxide (0.2 g) and N-bromosuccinimide (17.8 g, 0.10 mol) was heated at reflux temperature for 18 h. The reaction mixture was allowed to cool to room temperature, filtered and the solvent was evaporated in vacuo to give 3-bromo-1 1-diphenyl-1-propene in a quantitative yield.

Workup

  1. temperaturewas heated
  2. temperatureat reflux temperature for 18 h
  3. filtrationfiltered
  4. customthe solvent was evaporated in vacuo

Sources & evidence

ORD record
ord-49284c1892f1468eab03279d1f3b0fe0
Source dataset
uspto-grants-1993_03
Patent number
US05198451

Reaction notes

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