1,2-Difluoro-3-iodobenzene → (2,3-Difluorophenylsulfanyl)-triisopropylsilane

HRID 1616932Notes

Reaction equation

HRID 1616932 reaction equation
COC1([S:11][Si:12]([CH:19]([CH3:21])[CH3:20])([CH:16]([CH3:18])[CH3:17])[CH:13]([CH3:15])[CH3:14])C=CC=CC1OC.[F:22][C:23]1[CH:28]=[CH:27][CH:26]=[C:25](I)[C:24]=1[F:30]>>[F:30][C:24]1[C:23]([F:22])=[CH:28][CH:27]=[CH:26][C:25]=1[S:11][Si:12]([CH:16]([CH3:18])[CH3:17])([CH:19]([CH3:21])[CH3:20])[CH:13]([CH3:14])[CH3:15]

Participants

3

Reactant 2

HCID 190666581,2-Difluoro-3-iodobenzeneHCID 67323985(1,2-Dimethoxy-phenylsulfanyl)-triisopropyl-silane

Product 1

HCID 67322878(2,3-Difluorophenylsulfanyl)-triisopropylsilane

Procedure

Prepared as described for (1,2-dimethoxy-phenylsulfanyl)-triisopropyl-silane starting from 1,2-difluoro-3-iodobenzene.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-7494c01563f749ae96bd08a351310e30
Source dataset
uspto-grants-2014_07
Patent number
US08765779B2

Reaction notes

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