4-Methoxycarbonylphenylboronic acid → HCID 136367988, compound

HRID 1617509Notes

Reaction equation

HRID 1617509 reaction equation
Br[C:2]1[CH:7]=[CH:6][C:5]([CH:8]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[CH2:9]/[C:10](/[C:13]2[CH:18]=[CH:17][N:16]=[CH:15][CH:14]=2)=[N:11]\[OH:12])=[CH:4][CH:3]=1.[CH3:25][O:26][C:27]([C:29]1[CH:34]=[CH:33][C:32](B(O)O)=[CH:31][CH:30]=1)=[O:28]>>[CH3:25][O:26][C:27]([C:29]1[CH:34]=[CH:33][C:32]([C:2]2[CH:7]=[CH:6][C:5]([CH:8]([C:19]3[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=3)[CH2:9]/[C:10](=[N:11]\[OH:12])/[C:13]3[CH:18]=[CH:17][N:16]=[CH:15][CH:14]=3)=[CH:4][CH:3]=2)=[CH:31][CH:30]=1)=[O:28]

Participants

3

Reactant 2

HCID 27343694-Methoxycarbonylphenylboronic acidHCID 136167080HCID 136167080, compound

Product 1

HCID 136367988HCID 136367988, compound

Procedure

In analogy to example 19, from (E)-3-(4-bromo-phenyl)-3-phenyl-1-pyridin-4-yl-propan-1-one oxime (example 5) and 4-methoxycarbonylphenylboronic acid was prepared the title compound as yellow oil, MS (ESI+): m/z=437.2 ([M+H]+).

Sources & evidence

ORD record
ord-20329394280e48709d974d053106a740
Source dataset
uspto-grants-2014_07
Patent number
US08765730B2

Reaction notes

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