Ethyl cyanoacetate → HCID 367506, compound

HRID 1617532Notes

Reaction equation

[Br:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][CH:9]=1)[CH:5]=O.[C:10]([CH2:12][C:13]([O:15][CH2:16][CH3:17])=[O:14])#[N:11]>>[CH2:16]([O:15][C:13](=[O:14])[C:12]([C:10]#[N:11])=[CH:5][C:4]1[CH:7]=[CH:8][CH:9]=[C:2]([Br:1])[CH:3]=1)[CH3:17]

Participants

Reactant 2

HCID 7764Ethyl cyanoacetate

HCID 765833-Bromobenzaldehyde

Product 1

HCID 367506HCID 367506, compound

Procedure

In analogy to example 74, step 1, from 3-bromobenzaldehyde and ethyl cyanoacetate was prepared the title compound as a white solid, MS (EI+): m/z=279 ([M]+, 1Br).

Sources & evidence

ORD record: ord-5348943c7900412db4ef4b8e3538fa55
Source dataset: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08765730B2

Reaction notes

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