Allyl bromide → HCID 56949709, compound

Participants

Reaction Conditions

Reaction Steps

Crude isopropenyldiisopropylsilane (2.8 g), which was prepared as described in “Preparation of Isopropenyldiisopropylsilane—Method 2”, was taken up in allyl bromide (20 mL), and purged with N2 for 15 minutes. PdCl2 (32 mg, 1 mol %) was added and the suspension was heated to 60° C. for 12 hours. The suspension was concentrated by rotary evaporation, then taken up in pentane (40 mL) and filtered through quantitative filter paper, that was then rinsed with additional pentane (40 mL). Removal of solvent yielded 3.85 g of crude isopropenyldiisopropylbromosilane as a pale brown liquid.

Provenance & Evidence