HRID1625651

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID962

Water

H2O

HCID1004

Phosphoric acid

H3O4P

结构：CCOc1ccc(Nc2ccc(/C(=C3/C=CC(=[N+](CC)Cc4cccc(S(=O)(=O)[O-])c4)C=C3C)c3ccc(N(CC)Cc4cccc(S(=O)(=O)[O-])c4)cc3C)cc2)cc1.[Na+]

HCID6324599

未命名化合物

PRODUCTS

生成物

HCID1004

Phosphoric acid

H3O4P

收率 8.5%

$结构：CCOc1ccc(Nc2ccc(/C(=C3\C=CC(=[N+](CC)Cc4cccc(S(=O)(=O)O)c4)C=C3C)c3ccc(N(CC)Cc4cccc(S(=O)(=O)O)c4)cc3C)cc2)cc1$

HCID6333920

未命名化合物

收率 0.01%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID702

Ethanol

C2H6O

2 次

PROCEDURE

实验过程

To 100 mg Coomassie Brilliant Blue (G-250) was added 47 g ethanol, 85 g phosphoric acid and 850 g water. This solution was mixed for 20 minutes, to ensure all components were dissolved, resulting in a reagent comprising 0.01% (w/v) Coomassie Brilliant Blue G-250, 4.7% ethanol (w/v) and 8.5% (w/v) phosphoric acid. To this solution different dextrins were added as indicated in the specific examples.

WORKUP

后处理

additionThis solution was mixed for 20 minutes
dissolutionwere dissolved

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-f61266471ed845149ab6ff8cda4e6d6c
来源数据集: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08785203B2
来源说明: uspto-grants-2014_07

反应 SMILES

[CH3:1][CH2:2][N:3]([C:15]1[CH:20]=[CH:19][C:18](/[C:21](/[C:43]2[CH:48]=[CH:47][C:46]([NH:49][C:50]3[CH:55]=[CH:54][C:53]([O:56][CH2:57][CH3:58])=[CH:52][CH:51]=3)=[CH:45][CH:44]=2)=[C:22]2\[CH:23]=[CH:24][C:25]([CH:40]=[C:41]\2[CH3:42])=[N+:26]([CH2:29][C:30]2[CH:35]=[CH:34][CH:33]=[C:32]([S:36]([O-:39])(=[O:38])=[O:37])[CH:31]=2)[CH2:27][CH3:28])=[C:17]([CH3:59])[CH:16]=1)[CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[C:7]([S:11]([O-:14])(=[O:13])=[O:12])[CH:6]=1.[Na+].[P:61](=[O:65])([OH:64])([OH:63])[OH:62].O>C(O)C>[CH3:1][CH2:2][N:3]([C:15]1[CH:20]=[CH:19][C:18](/[C:21](/[C:43]2[CH:44]=[CH:45][C:46]([NH:49][C:50]3[CH:55]=[CH:54][C:53]([O:56][CH2:57][CH3:58])=[CH:52][CH:51]=3)=[CH:47][CH:48]=2)=[C:22]2/[CH:23]=[CH:24][C:25]([CH:40]=[C:41]/2[CH3:42])=[N+:26]([CH2:29][C:30]2[CH:35]=[CH:34][CH:33]=[C:32]([S:36]([OH:39])(=[O:37])=[O:38])[CH:31]=2)[CH2:27][CH3:28])=[C:17]([CH3:59])[CH:16]=1)[CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[C:7]([S:11]([OH:14])(=[O:13])=[O:12])[CH:6]=1.[P:61](=[O:62])([OH:65])([OH:64])[OH:63]