Benzo(B)Thiophene → HCID 66608087, compound

HRID 1625802Notes

Reaction equation

HRID 1625802 reaction equation
[Br:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][C:9]=1[CH3:10])[CH:5]=O.[CH:11]1[CH:12]=[CH:13][C:14]2[S:19][CH:18]=[CH:17][C:15]=2[CH:16]=1>>[S:19]1[C:18]([CH2:5][C:4]2[CH:7]=[CH:8][C:9]([CH3:10])=[C:2]([Br:1])[CH:3]=2)=[CH:17][C:15]2[CH:16]=[CH:11][CH:12]=[CH:13][C:14]1=2

Participants

3

Reactant 2

HCID 7221Benzo(B)ThiopheneHCID 8167653-Bromo-4-methylbenzaldehyde

Product 1

HCID 66608087HCID 66608087, compound

Procedure

The above 3-bromo-4-methylbenzaldehyde and thianaphthene were treated in a manner similar to Reference Example 7 to give (Benzo[b]thiophen-2-ylmethyl)-3-bromo-4-methylbenzene as a colorless solid.

Sources & evidence

ORD record
ord-a6806d593b314e8e8c331c720403e4dc
Source dataset
uspto-grants-2014_07
Patent number
US08785403B2

Reaction notes

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