Benzo(B)Thiophene → HCID 66608908, compound

HRID 1625816Notes

Reaction equation

HRID 1625816 reaction equation
CON(C)[C:4](=O)[C:5]1[CH:10]=[C:9]([Br:11])[CH:8]=[CH:7][C:6]=1[CH2:12][CH3:13].[CH:16]1[CH:17]=[CH:18][C:19]2[S:24][CH:23]=[CH:22][C:20]=2[CH:21]=1>>[S:24]1[C:23]([CH2:4][C:5]2[CH:10]=[C:9]([Br:11])[CH:8]=[CH:7][C:6]=2[CH2:12][CH3:13])=[CH:22][C:20]2[CH:21]=[CH:16][CH:17]=[CH:18][C:19]1=2

Participants

3

Reactant 2

HCID 7221Benzo(B)ThiopheneHCID 86028267HCID 86028267, compound

Product 1

HCID 66608908HCID 66608908, compound

Procedure

The above N-methoxy-N-methyl-5-bromo-2-ethylbenzamide and thianaphthene were treated in a manner similar to Reference Example 45 to give 1-(Benzo[b]thiophen-2-ylmethyl)-5-bromo-2-ethylbenzene as oil.

Sources & evidence

ORD record
ord-b6403c9b0dd049be9504b58d94994bf7
Source dataset
uspto-grants-2014_07
Patent number
US08785403B2

Reaction notes

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