HuagongsheHuagongshe Chemistry Print Report · For research reference only
(4-Bromophenyl)boronic acid → Ethyl (4'-bromobiphenyl-4-yl)acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (4-Bromophenyl)boronic acid | HCID 79599 | — |
| Reactant | Ethyl (4-iodophenyl)acetate | HCID 14974990 | — |
| Product | Ethyl (4'-bromobiphenyl-4-yl)acetate | HCID 70818737 | 71% |
Reaction Steps
In accordance with Example 11-(1), but using ethyl 4-iodophenylacetate instead of 4-bromobenzyl bromide, and (4-bromophenyl)boronic acid instead of [3-(hydroxymethyl)phenyl]boronic acid, ethyl (4′-bromobiphenyl-4-yl)acetate (yield 71%) was afforded as a white solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08785462B2 |
| Source dataset | uspto-grants-2014_07 |
| ORD ID | ord-0262de864bae46b89b5c44674992fbe0 |
| Source note | uspto-grants-2014_07 |