(5-Bromo-2-methylphenyl)methanol → 5-Bromo-2-methylbenzaldehyde

Participants

Role	Name	HCID	Charge
Reactant	(5-Bromo-2-methylphenyl)methanol	HCID 12993770	—
Catalyst	HCID 178418406	HCID 178418406	—
Solvent	1,4-Dioxane	HCID 31275	—
Product	5-Bromo-2-methylbenzaldehyde	HCID 10420289	—

Reaction Conditions

Temperature	80 °C

Reaction Steps

To a solution of INT 29 (19.3 g, 96 mmol) in dioxane (800 mL) was added manganese dioxide (50.2 g, 577 mmol). The reaction mixture was stirred at 80° C. for 3 h. The mixture was filtered over Celite and the filtrate was concentrated to give INT 30.

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US08791100B2
Source dataset	uspto-grants-2014_07
ORD ID	ord-95927e9326104a6884c9aac5a6a5158f
Source note	uspto-grants-2014_07