HCID 86600581, compound → HCID 67049543, compound

HRID 1629899Notes

Reaction equation

HRID 1629899 reaction equation
C(OC(CO[N:8]=[C:9]([C:14]1[CH:18]=[CH:17][N:16]([CH3:19])[N:15]=1)[C:10]([O:12][CH3:13])=[O:11])=O)C.[H][H]>C(O)C.[Pd]>[NH2:8][CH:9]([C:14]1[CH:18]=[CH:17][N:16]([CH3:19])[N:15]=1)[C:10]([O:12][CH3:13])=[O:11]

Participants

5

Reactant 2

HCID 86600581HCID 86600581, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 67049543HCID 67049543, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

2.61 g (9.69 mmol) methyl ethoxycarbonyl-methoxyimino-(1-methyl-pyrazol-3-yl)-acetate are hydrogenated in 60 ml of ethanol with 1.1 g 5% palladium charcoal for 16 h at 50° C. under 3.4 bars pressure in a hydrogen atmosphere. Then the mixture is suction filtered and the filtrate is evaporated down completely i. vac.

Workup

  1. filtrationfiltered
  2. customthe filtrate is evaporated down completely i

Sources & evidence

ORD record
ord-b77605236cf1461ea208f320a6e576e3
Source dataset
uspto-grants-2014_07
Patent number
US08791103B2

Reaction notes

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