Isobutyric Acid → HCID 57954475, compound

HRID 1630428Notes

Reaction equation

[C:1]1(=[N:7][OH:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.[Pb+4].[C:26]([OH:31])(=[O:30])[CH:27]([CH3:29])[CH3:28]>>[C:26]([O:31][C:1]1([N:7]=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1)(=[O:30])[CH:27]([CH3:29])[CH3:28]

Participants

Reactant 3

HCID 6590Isobutyric Acid

HCID 7517Cyclohexanone Oxime

HCID 178418268HCID 178418268, compound

Product 1

HCID 57954475HCID 57954475, compound

Procedure

1-Nitrosocyclohexyl isobutyrate was prepared from cyclohexanone oxime, lead tetraacetate and isobutyric acid using conditions of General Method 3. 1H NMR (400 MHz, chloroform-d) δ 2.68-2.79 (1H, sept, 7.0 Hz), 1.71-1.93 (8H, m), 1.48-1.62 (2H, m), 1.29 (3H, s), 1.27 (3H, s).

Sources & evidence

ORD record: ord-85954296ce184e179680a1eb306508b7
Source dataset: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08791134B2

Reaction notes

Loading…