HuagongsheHuagongshe Chemistry Print Report · For research reference only
3,3,3-Trifluoropropionic acid → 4-Nitrosotetrahydro-2H-pyran-4-yl 3,3,3-trifluoropropanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3,3,3-Trifluoropropionic acid | HCID 2777972 | — |
| Reactant | N-(oxan-4-ylidene)hydroxylamine | HCID 12298558 | — |
| Reactant | HCID 178418268 | HCID 178418268 | — |
| Product | 4-Nitrosotetrahydro-2H-pyran-4-yl 3,3,3-trifluoropropanoate | HCID 57954492 | — |
Reaction Steps
4-Nitrosotetrahydro-2H-pyran-4-yl 3,3,3-trifluoropropanoate was prepared from tetrahydro-pyran-4-one oxime, lead tetraacetate and 3,3,3-trifluoropropionic acid using conditions of General Method 3. 1H NMR (360 MHz, chloroform-d) δ 3.94-4.17 (2H, m), 3.54-3.79 (2H, m), 3.37 (2H, q), 2.23-2.43 (2H, m), 1.65-1.96 (2H, m).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08791134B2 |
| Source dataset | uspto-grants-2014_07 |
| ORD ID | ord-c2587026ef6949d0bfd103edd6d87e26 |
| Source note | uspto-grants-2014_07 |