HuagongsheHuagongshe Chemistry Print Report · For research reference only
4,4,4-Trifluorobutanoic acid → 4-Nitrosotetrahydro-2H-pyran-4-yl 4,4,4-trifluorobutanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4,4,4-Trifluorobutanoic acid | HCID 2777085 | — |
| Reactant | N-(oxan-4-ylidene)hydroxylamine | HCID 12298558 | — |
| Reactant | HCID 178418268 | HCID 178418268 | — |
| Product | 4-Nitrosotetrahydro-2H-pyran-4-yl 4,4,4-trifluorobutanoate | HCID 57954490 | — |
Reaction Steps
4-Nitrosotetrahydro-2H-pyran-4-yl 4,4,4-trifluorobutanoate was prepared from tetrahydro-pyran-4-one oxime, lead tetraacetate and 4,4,4,-trifluorobutyric acid using conditions of General Method 3. 1H NMR (250 MHz, chloroform-d) δ 3.91-4.19 (2H, m), 3.48-3.83 (2H, m), 2.71-2.94 (2H, m), 2.36-2.67 (2H, m), 2.15-2.34 (2H, m), 1.63-1.96 (2H, m).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08791134B2 |
| Source dataset | uspto-grants-2014_07 |
| ORD ID | ord-c71dbc557924425ea74b82575eaf1d18 |
| Source note | uspto-grants-2014_07 |