Cyclohexanone Oxime → HCID 57954500, compound

HRID 1630437Notes

Reaction equation

[C:1]1(=[N:7][OH:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.[Pb+4].[F:26][C:27]([F:35])([F:34])[C:28]([F:33])([F:32])[C:29]([OH:31])=[O:30]>>[F:32][C:28]([F:33])([C:27]([F:35])([F:34])[F:26])[C:29]([O:31][C:1]1([N:7]=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1)=[O:30]

Participants

Reactant 3

HCID 7517Cyclohexanone Oxime

HCID 62356Pentafluoropropionic acid

HCID 178418268HCID 178418268, compound

Product 1

HCID 57954500HCID 57954500, compound

Procedure

1-Nitrosocyclohexyl 2,2,3,3,3-pentafluoropropanoate was prepared from cyclohexanone oxime, lead tetraacetate and pentafluoropropionic acid using conditions of General Method 3. 1H NMR (360 MHz, chloroform-d) δ 2.35-2.31 (2H, m), 1.77-2.00 (4H, m), 1.49-1.72 (4H, m).

Sources & evidence

ORD record: ord-dd517f251ec94e9fb02380b3faedd6f2
Source dataset: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08791134B2

Reaction notes

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