HuagongsheHuagongshe Chemistry Print Report · For research reference only
Pivalic acid → 4-Nitrosotetrahydro-2H-pyran-4-yl pivalate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Pivalic acid | HCID 6417 | — |
| Reactant | N-(oxan-4-ylidene)hydroxylamine | HCID 12298558 | — |
| Reactant | HCID 178418268 | HCID 178418268 | — |
| Product | 4-Nitrosotetrahydro-2H-pyran-4-yl pivalate | HCID 57954495 | — |
Reaction Steps
4-Nitrosotetrahydro-2H-pyran-4-yl pivalate was prepared from tetrahydro-pyran-4-one oxime, lead tetraacetate and trimethylacetic acid using conditions of General Method 3. 1H NMR (360 MHz, chloroform-d) δ 3.91-4.14 (2H, m), 3.57-3.77 (2H, m), 2.10-2.29 (2H, m), 1.75-1.93 (2H, m), 1.34 (9H, s).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08791134B2 |
| Source dataset | uspto-grants-2014_07 |
| ORD ID | ord-5c9757b355ca46419804a0022df88e22 |
| Source note | uspto-grants-2014_07 |