Cyclohexanone Oxime → HCID 57954455, compound

HRID 1630444Notes

Reaction equation

HRID 1630444 reaction equation
[C:1]1(=[N:7][OH:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.[Pb+4].[P:26]([O-:38])([O:33][CH2:34][CH2:35][CH2:36][CH3:37])([O:28][CH2:29][CH2:30][CH2:31][CH3:32])=[O:27]>>[P:26]([O:38][C:1]1([N:7]=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1)([O:28][CH2:29][CH2:30][CH2:31][CH3:32])([O:33][CH2:34][CH2:35][CH2:36][CH3:37])=[O:27]

Participants

4

Reactant 3

HCID 7517Cyclohexanone OximeHCID 3790919Dibutyl phosphate anionHCID 178418268HCID 178418268, compound

Product 1

HCID 57954455HCID 57954455, compound

Procedure

Dibutyl 1-nitrosocyclohexyl phosphate was prepared from cyclohexanone oxime, lead tetraacetate and dibutyl phosphate using conditions of General Method 3. 1H NMR (400 MHz, chloroform-d) δ 4.12-4.21 (1H, m), 4.00 (3H, q, 6.7 Hz), 1.61-1.79 (6H, m), 1.36-1.48 (5H, m), 1.25-1.35 (4H, m), 0.86-0.97 (9H, m).

Sources & evidence

ORD record
ord-99ba78a0b39e428bba5d887328447e29
Source dataset
uspto-grants-2014_07
Patent number
US08791134B2

Reaction notes

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