Acetic Acid → 4-Chloro-3-methylbut-2-en-1-yl acetate

HRID 1632335Notes

Reaction equation

[Cl:1]OC(C)(C)C.[CH2:7]=[CH:8][C:9](=[CH2:11])[CH3:10].[C:12]([OH:15])(=[O:14])[CH3:13]>>[Cl:1][CH2:11][C:9]([CH3:10])=[CH:8][CH2:7][O:14][C:12](=[O:15])[CH3:13]

Participants

Reactant 3

HCID 176Acetic Acid

HCID 6557Isoprene

HCID 521297Tert-Butyl hypochlorite

Product 1

HCID 534009324-Chloro-3-methylbut-2-en-1-yl acetate

Procedure

1-Chloro-2-methyl-4-acetoxy-2-butene was prepared in accordance with the process described in J. Am. Chem. Soc. 72 4610 (1950) by reacting t-butyl hypochlorite with isoprene in an acetic acid medium.

Sources & evidence

ORD record: ord-6cc953fa05b748e4b0901a9f8b408155
Source dataset: uspto-grants-1984_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04474983

Reaction notes

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