Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tributylstannane → (E)-1-tri-n-butylstannyl-3-triethylsilyloxy-1-octene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tributylstannane | HCID 5948 | — |
| 반응물 | Azobisisobutyronitrile | HCID 6547 | — |
| 반응물 | 3-Triethylsilyloxy-1-octyne | HCID 12675346 | — |
| 생성물 | (E)-1-tri-n-butylstannyl-3-triethylsilyloxy-1-octene | HCID 20442056 | — |
반응 단계
A solution of 20 g of 3-triethylsilyloxy-1-octyne, 150 mg of azobisisobutyronitrile, and 30 ml of tri-n-butyltin hydride is magnetically stirred un er an argon atmosphere at 140° C. for 2 hours, (EXOTHERMIC), then cooled to ambient temperature. The excess tin hydride is removed by distillation (~70°/1.0 mm). The residue is purified by distillation to provide 36.5 g of the oil (bp 165° C. at 0.05 mm).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04477388 |
| 출처 데이터셋 | uspto-grants-1984_10 |
| ORD ID | ord-dfe125626b584e11bb602936496cbed6 |
| 출처 메모 | uspto-grants-1984_10 |