HCID 13340319, compound → HCID 13340320, compound

HRID 1632712Notes

Reaction equation

HRID 1632712 reaction equation
Br[CH:2]1[C:8](=[O:9])[C:7]2[CH:10]=[C:11]([CH3:15])[C:12]([CH3:14])=[CH:13][C:6]=2[NH:5][C:4](=[O:16])[CH2:3]1>C(Cl)(Cl)Cl>[CH3:15][C:11]1[C:12]([CH3:14])=[CH:13][C:6]2[NH:5][C:4](=[O:16])[CH:3]=[CH:2][C:8](=[O:9])[C:7]=2[CH:10]=1

Participants

3

Reactant 1

HCID 13340319HCID 13340319, compound

Product 1

HCID 13340320HCID 13340320, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

To a chloroform solution of the 4-bromo-2,3,4,5-tetrahydro-7,8-dimethyl-2,5-dioxobenz(f)azepine was added hydrated sodium acetate. On shaking, filtration, and storage, yellow 2,5-dihydro-7,8-dimethylbenz(f)azepine-2,5-dione, mp 258° C. (from propanol) was deposited.

Workup

  1. filtrationfiltration, and storage, yellow 2,5-dihydro-7,8-dimethylbenz(f)azepine-2,5-dione, mp 258° C. (from propanol)

Sources & evidence

ORD record
ord-9824cf4e586742179e1df79168bd508f
Source dataset
uspto-grants-1984_10
Patent number
US04477446

Reaction notes

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