Acrylonitrile → HCID 11728434, compound

HRID 1632927Notes

Reaction equation

HRID 1632927 reaction equation
[C:1](I)([C:4]([C:7]([C:10]([C:13]([C:16]([F:19])([F:18])[F:17])([F:15])[F:14])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2].[C:21](#[N:24])[CH:22]=[CH2:23]>[Zn].C([O-])(=O)C.[Cu+2].C([O-])(=O)C.[Zn].[Cu]>[C:1]([CH2:23][CH2:22][C:21]#[N:24])([C:4]([C:7]([C:10]([C:13]([C:16]([F:19])([F:18])[F:17])([F:15])[F:14])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2]

Participants

6

Reactant 2

HCID 7855AcrylonitrileHCID 677331,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane

Product 1

HCID 11728434HCID 11728434, compound

Reagents, catalysts & solvents 3

HCID 8895Cupric acetateCatalystHCID 23994ZincCatalystHCID 10290809Zinc copper coupleCatalyst

Procedure

A series of tests was carried out according to the operating method of Example 1, but by modifying the nature of the solvent. These tests were made by dispersing 4 g. of coarse zinc powder in a solution of 100 mg of copper acetate in 30 ml of acid, by varying the latter. The dispersion of the zinc/copper metal pair is cooled to ambient temperature, and a mixture of 23 g. of C6F13I (0.05 mole) and 2.7 g. of acrylonitrile are introduced into the above dispersion, with agitation, during a period of one hour. One hour after termination of the addition of the two reactants, the reaction mixture is washed with water and analyzed by nuclear magentic resonance. The results are indicated in Table I in which the indicated percentages are molar percentages.

Workup

  1. additionby dispersing 4 g
  2. additiona mixture of 23 g
  3. additionOne hour after termination of the addition of the two reactants
  4. washthe reaction mixture is washed with water

Sources & evidence

ORD record
ord-bf3c25323cab435da426f46aed8daba8
Source dataset
uspto-grants-1984_10
Patent number
US04478760

Reaction notes

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