Ethanol → Ethyl 4-(2-oxopropyl)benzoate

HRID 1633104Notes

Reaction equation

[C:1]([C:6]1[CH:11]=[CH:10][C:9]([CH:12]=[C:13]([N+]([O-])=O)[CH3:14])=[CH:8][CH:7]=1)([O:3][CH2:4][CH3:5])=[O:2].C([OH:20])C>>[C:1]([C:6]1[CH:11]=[CH:10][C:9]([CH2:12][C:13](=[O:20])[CH3:14])=[CH:8][CH:7]=1)([O:3][CH2:4][CH3:5])=[O:2]

Participants

Reactant 2

HCID 702Ethanol

HCID 53678063HCID 53678063, compound

Product 1

HCID 20134204Ethyl 4-(2-oxopropyl)benzoate

Procedure

The title compound was prepared in an identical manner to that described in Description 2 using 1-(4-carboethoxyphenyl)-2-nitroprop-1-ene and replacing the solvent with ethanol. γ (CDCl3) 8.62 (3H, t, J=7 Hz), 7.87 (3H, s), 6.29 (2H, s), 5.64 (2H, q, J=7 Hz), 2.76 (2H, d, J=9 Hz), 2.0 (2H, d, J=9 Hz).

Sources & evidence

ORD record: ord-d015ca739bbb47579c38e6dbe438dbaf
Source dataset: uspto-grants-1984_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04478849

Reaction notes

Loading…