Triethylamine → HCID 13367235, compound

Participants

Reaction Conditions

Reaction Steps

To a solution of 62 g (0.6 mole) of sulfur dichloride in 200 ml of methylene chloride cooled to 0° C. under a nitrogen atmosphere was added a solution of 75 g (0.4 mole) of 2-ethylhexyl N-methylcarbamate and 44.5 g (0.44 mole) of triethylamine in 100 ml of methylene chloride at -10° to 3° C. The addition took 2 hr. After stirring for 1 hr at 5° C., the mixture was filtered under a positive nitrogen atmosphere, and the filtrate was concentrated. The product was extracted into 200 ml of hexanes and the solid triethylamine hydrochloride was filtered. The filtrate was concentrated to give 105.4 g of 2-ethylhexyl N-chlorothio-N-methylcarbamate.

Provenance & Evidence