Sodium Hydroxide → HCID 53963518, compound

HRID 1633326Notes

Reaction equation

HRID 1633326 reaction equation
[OH-].[Na+].[C:3]([C:7]1[CH:39]=[CH:38][C:10]([O:11][CH2:12][CH2:13][CH2:14][CH2:15][Si:16]([CH3:37])([CH3:36])[O:17][Si:18]([CH3:35])([CH3:34])[CH2:19][CH2:20][CH2:21][CH2:22][O:23][C:24]2[CH:29]=[CH:28][C:27]([C:30]([O:32]C)=[O:31])=[CH:26][CH:25]=2)=[CH:9][CH:8]=1)([O:5]C)=[O:4]>O>[C:3]([C:7]1[CH:8]=[CH:9][C:10]([O:11][CH2:12][CH2:13][CH2:14][CH2:15][Si:16]([CH3:36])([CH3:37])[O:17][Si:18]([CH3:35])([CH3:34])[CH2:19][CH2:20][CH2:21][CH2:22][O:23][C:24]2[CH:25]=[CH:26][C:27]([C:30]([OH:32])=[O:31])=[CH:28][CH:29]=2)=[CH:38][CH:39]=1)([OH:5])=[O:4]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 54370017HCID 54370017, compound

Product 1

HCID 53963518HCID 53963518, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A reaction mixture consisting of 8 parts NaOH in 200 parts H2O and 54.6 parts of 1,3-bis(p-carbomethoxyphenoxybutyl)tetramethyldisiloxane (see Example XII) were combined and heated to reflux. The mixture was initially heterogeneous but became homogeneous after three hours, at which time the reaction was terminated, extracted two times with 100 ml. toluene and acidified with excess HCl. A white precipitate formed, which was filtered and recrystallized from pentane. The structure was confirmed by I.R. and N.M.R.

Workup

  1. temperatureheated to reflux
  2. customthe reaction was terminated
  3. extractionextracted two times with 100 ml
  4. customA white precipitate formed
  5. filtrationwhich was filtered
  6. customrecrystallized from pentane

Sources & evidence

ORD record
ord-eb7cfd7688d14a76b9d5411f62d50094
Source dataset
uspto-grants-1984_10
Patent number
US04480009

Reaction notes

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