(2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-[(E)-3-phenylprop-2-enoxy]oxane-3,4,5-triol → Benzene, ethenyl-, polymer with 1,3-butadiene

HRID 1633715Notes

Reaction equation

HRID 1633715 reaction equation
[CH:1]1[CH:6]=CC(/C=C/CO[C@@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)=[CH:3][CH:2]=1.[O-]O.[CH:24]([C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][C:28]=1C(C)C)(C)[CH3:25]>>[CH2:6]=[CH:1][CH:2]=[CH2:3].[CH2:25]=[CH:24][C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1

Participants

3

Reactant 2

HCID 5280656(2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-[(E)-3-phenylprop-2-enoxy]oxane-3,4,5-triol2×HCID 57376481Diisopropyl benzene hydroperoxide

Product 1

HCID 62697Benzene, ethenyl-, polymer with 1,3-butadiene

Procedure

1.0 wt. parts of rosin salt as an emulsifier was added after 3 hours from the addition of diisopropylbenzene hydroperoxide as an oxidant at an initial reaction step, and thereafter 1.5 wt. parts of rosin salt were added after 8 hours.

Workup

  1. customreaction step

Sources & evidence

ORD record
ord-2dacceb923684902a30397f8fd1b16b3
Source dataset
uspto-grants-2003_01
Patent number
US06503968B1

Reaction notes

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