Methyl 3-(chlorocarbonyl)benzoate → HCID 18677342, compound

HRID 1634134Notes

Reaction equation

HRID 1634134 reaction equation
[Cl:1][C:2]1[C:12]([Cl:13])=[CH:11][C:5](/[CH:6]=[CH:7]/N(C)C)=[C:4]([N+:14]([O-])=O)[CH:3]=1.C[O:18][C:19]([C:21]1[CH:22]=[C:23]([CH:27]=[CH:28][CH:29]=1)C(Cl)=O)=[O:20]>>[Cl:13][C:12]1[CH:11]=[C:5]2[C:4](=[CH:3][C:2]=1[Cl:1])[NH:14][C:7]([C:28]1[CH:29]=[C:21]([CH:22]=[CH:23][CH:27]=1)[C:19]([OH:20])=[O:18])=[CH:6]2

Participants

3

Reactant 2

HCID 15563901Methyl 3-(chlorocarbonyl)benzoateHCID 22675057HCID 22675057, compound

Product 1

HCID 18677342HCID 18677342, compound

Procedure

Starting from trans-4,5-dichloro-2-nitro-β-dimethylaminostyrene and 3-(methoxycarbonyl)benzoyl chloride and following successively the procedures of Descriptions 2, 3 and 4 afforded the title compound as a beige solid which was used without further purification in the next step.

Sources & evidence

ORD record
ord-5d69773f8a1241d088f063143b33b58e
Source dataset
uspto-grants-2003_01
Patent number
US06506758B2

Reaction notes

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