HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-Butyl hydroperoxide → Benzene, 2-(bromomethyl)-1-methoxy-3-nitro-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-Butyl hydroperoxide | HCID 6410 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 2-Methyl-3-nitroanisole | HCID 78554 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | Benzene, 2-(bromomethyl)-1-methoxy-3-nitro- | HCID 186047 | 10.2% |
Reaction Steps
A solution of 2-methoxy-6-nitrotoluene (28.2 g, 159 mmol) and N-bromosuccinimide (26.5 g, 159 mmol) in 350 mL CCl4 was treated with a catalytic amount of t-butylhydroperoxide and irradiated with a floodlamp while stirring for 3 hours. The solids formed were filtered and the filtrate concentrated to give 4.0 g of a yellow solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06506901B2 |
| Source dataset | uspto-grants-2003_01 |
| ORD ID | ord-143f1584979841c98927bbcb02fdb0d3 |
| Source note | uspto-grants-2003_01 |