HuagongsheHuagongshe Chemistry Print Report · For research reference only
(4-Benzoyl-2-nitro-phenyl)-carbamic acid tert.-butyl ester → Carbamic acid,(2-amino-4-benzoylphenyl)-,1,1-dimethylethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (4-Benzoyl-2-nitro-phenyl)-carbamic acid tert.-butyl ester | HCID 69592825 | — |
| Catalyst | Nickel | HCID 935 | — |
| Product | Carbamic acid,(2-amino-4-benzoylphenyl)-,1,1-dimethylethyl ester | HCID 69592848 | 105% |
Reaction Steps
Prepared from (4-benzoyl-2-nitro-phenyl)-carbamic acid tert.-butyl ester (Example D1) (280 mg, 0.82 mmol) by catalytic hydrogenation with Raney-Ni according to the general procedure G (method a). Obtained as a yellow foam (269 mg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06509328B1 |
| Source dataset | uspto-grants-2003_01 |
| ORD ID | ord-1eeadc59131a4b1a8bfdad7db3ed0869 |
| Source note | uspto-grants-2003_01 |