HCID 131721711, compound → L-Glutamine

Participants

Reaction Steps

The protected form of L-Gln-didemnin A (3.20 mg, 2.60 umol) was dissolved in isopropyl alcohol (0.50 mL) and 10% Pd/C catalyst (3.00 mg) was added. The solution was hydrogenated for 3 h, then the catalyst was removed by filtration over celite and solvent was removed to afford L-Gln-DA (2.30 mg, 88%); FABMS 1071.5 (M+H); HRFABMS Calcd for C54H87N8O14 (M+H) 1071.6341, Found 1071.6342.

Provenance & Evidence