HuagongsheHuagongshe Chemistry Print Report · For research reference only
4,5-Dimethyl-1,2-phenylenediamine → 2,3-Dimethyl-7-trifluoromethylphenazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4,5-Dimethyl-1,2-phenylenediamine | HCID 76635 | — |
| Reactant | 4-Bromo-3-nitrobenzotrifluoride | HCID 520706 | — |
| Reactant | Diamino diphenylamine | HCID 118255529 | — |
| Solvent | Hydrochloric Acid | HCID 313 | — |
| Product | 2,3-Dimethyl-7-trifluoromethylphenazine | HCID 19350150 | — |
Reaction Steps
The 2,3-dimethyl-7-trifluoromethylphenazine was prepared in a 3-step process, starting with 4,5-dimethyl-1,2-phenylenediamine and 3-nitro-4-bromobenzotrifluoride. The nucleophilic substitution product being the biarylamine was then reduced with stannous chloride in conc. HCl to the diamino diphenylamine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06037471 |
| Source dataset | uspto-grants-2000_03 |
| ORD ID | ord-487a8b14a6574767bba97188b9647452 |
| Source note | uspto-grants-2000_03 |