HRID1637391

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：COc1cc(COC(=O)Cl)c([N+](=O)[O-])cc1OC

HCID3084878

((Nitroveratryl)oxy)chlorocarbamate

C10H10ClNO6

结构：CS(=O)(=O)N(CCCl)N(C(=O)Oc1ccccc1)S(C)(=O)=O

HCID9799547

未命名化合物

PRODUCTS

生成物

结构：COc1cc(COC(=O)N(N(CCCl)S(C)(=O)=O)S(C)(=O)=O)c([N+](=O)[O-])cc1OC

HCID9935287

未命名化合物

PROCEDURE

实验过程

1,2-Bis(methylsulfonyl)-1-(2-chloroethyl)-2-[(4,5-dimethoxy-2-nitrobenzyloxy)carbonyl]hydrazine (compound 12) was prepared by reacting 4,5-dimethoxy-2-nitrobenzyl chloroformate with compound 2 using a procedure similar to that described for compound 10d. The product was recrystallized from ethanol, and the Mp was about 154° C. Yield was about 17.6% by weight. 1H NMR (acetone d6): δ 7.7 and 7.4 (2H, 2s, aromatic H), 5.8 (2H, d, ArCH2), 3.7-4.1 (4H, m, CH2CH2Cl), 3.9-4.0 (6H, 2s, 2 OCH3), and 3.5 and 3.2 (6H, 2s, 2 CH3SO2).

WORKUP

后处理

customThe product was recrystallized from ethanol