1,2-Phenylenedimethanamine → 1,3-Benzenedimethanamine

HRID 1638124Notes

Reaction equation

HRID 1638124 reaction equation
[CH3:1][CH:2]([CH2:4][C@@H:5]1[NH:28][C:26](=[O:27])[C@@H:25]([CH:29]([CH3:31])[CH3:30])[O:24][C:22](=[O:23])[C@H:21]([CH2:32][C:33]2[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=2)[N:20]([CH3:39])[C:18](=[O:19])[C@@H:17]([CH:40]([CH3:42])[CH3:41])[O:16][C:14](=[O:15])[C@H:13]([CH2:43][C:44]2[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=2)[N:12]([CH3:50])[C:10](=[O:11])[C@@H:9]([CH:51]([CH3:53])[CH3:52])[O:8][C:6]1=[O:7])[CH3:3].[C:54]1(CN)[C:55]([CH2:60][NH2:61])=[CH:56][CH:57]=[CH:58][CH:59]=1>C(Cl)Cl>[CH3:3][CH:2]([CH2:4][C@@H:5]1[NH:28][C:26](=[O:27])[C@@H:25]([CH:29]([CH3:30])[CH3:31])[O:24][C:22](=[O:23])[C@H:21]([CH2:32][C:33]2[CH:34]=[CH:35][CH:36]=[CH:37][CH:38]=2)[N:20]([CH3:39])[C:18](=[O:19])[C@@H:17]([CH:40]([CH3:41])[CH3:42])[O:16][C:14](=[O:15])[C@H:13]([CH2:43][C:44]2[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=2)[N:12]([CH3:50])[C:10](=[O:11])[C@@H:9]([CH:51]([CH3:53])[CH3:52])[O:8][C:6]1=[O:7])[CH3:1].[CH:59]1[CH:54]=[C:55]([CH2:60][NH2:61])[CH:56]=[C:57]([CH2:10][NH2:12])[CH:58]=1

Participants

5

Reactant 2

HCID 4319681,2-PhenylenedimethanamineHCID 3007987HCID 3007987, compound

Product 2

HCID 151331,3-BenzenedimethanamineHCID 3007987HCID 3007987, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

By using 1-phenyl-1,2,3,4-tetrahydroquinoline-6-carboxyaldehyde-1',1'-diphenylhydrazone (C-2) as a charge-transfer substance, (PC-1) as a binder resin material and xylylenediamine (MXDA) as a crosslinking agent, a solution of (C-2):(PC-1):MXDA:methylene chloride=1:1:0.2:8 (weight ratio) was produced to use it as a coating fluid. On standing for one month, the coating fluid did not whiten nor set to gel.

Sources & evidence

ORD record
ord-92094699e5e84b5ca0dadf3bef09785f
Source dataset
uspto-grants-2000_03
Patent number
US06043334

Reaction notes

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