Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tetrahydrophthalic anhydride → N-(3-(allyloxy)-4-chlorophenyl)-3,4,5,6-tetrahydrophthalimide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tetrahydrophthalic anhydride | HCID 6810 | — |
| 반응물 | 4-Chloro-3-[(prop-2-en-1-yl)oxy]aniline | HCID 54496113 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | N-(3-(allyloxy)-4-chlorophenyl)-3,4,5,6-tetrahydrophthalimide | HCID 12881900 | — |
반응 단계
A mixture of 4.4 g of THPA, 5.3 g of 3B and 60 mL of glacial acetic acid was refluxed for 1 hour, then poured into 300 mL of ice water. The resulting mixture was allowed to stand for 10 minutes, then filtered. The collected solid was washed with cold water, dried under reduced pressure and recrystallized from ethyl acetate/hexane, to give N-(3-(allyloxy)-4-chlorophenyl)-3,4,5,6-tetrahydrophthalimide (3C), as yellow crystals, m.p.: 118.5°-120° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04881967 |
| 출처 데이터셋 | uspto-grants-1989_11 |
| ORD ID | ord-897bd9c811884df3a663d3eced29ab1c |
| 출처 메모 | uspto-grants-1989_11 |