Thionyl Chloride → HCID 54013165, compound

HRID 1638950Notes

Reaction equation

HRID 1638950 reaction equation
[C:1]([O:4][C:5]1[CH:6]=[C:7]([C:17]([OH:19])=O)[C:8]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:9][CH:10]=1)(=[O:3])[CH3:2].O=S(Cl)[Cl:22]>>[C:1]([O:4][C:5]1[CH:6]=[C:7]([C:17]([Cl:22])=[O:19])[C:8]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:9][CH:10]=1)(=[O:3])[CH3:2]

Participants

3

Reactant 2

HCID 24386Thionyl ChlorideHCID 19898369HCID 19898369, compound

Product 1

HCID 54013165HCID 54013165, compoundYield 114.3%

Procedure

5.7 g (2.23×10-2 mol) of p-acetyloxybiphenylcarboxylic acid was added to 20 g (1.68×10-1 mol) of SOCl2 and the mixture was heated at reflux for 3.5 hours. After cooling, the solvent was evaporated to give 7.0 g of p-acetyloxybiphenylcarboxylic acid chloride.

Workup

  1. temperaturethe mixture was heated
  2. temperatureat reflux for 3.5 hours
  3. temperatureAfter cooling
  4. customthe solvent was evaporated

Sources & evidence

ORD record
ord-39f3c5693ce24e78bfb24cf9433bc792
Source dataset
uspto-grants-1989_11
Patent number
US04882085

Reaction notes

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