HRID1639153

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：[O-2].[Ti+4].c1ccc2c(c1)-c1nc3nc(nc4[n-]c(nc5[n-]c(nc-2n1)c1ccccc51)c1ccccc41)-c1ccccc1-3

HCID178514814

未命名化合物

PRODUCTS

生成物

结构：[Ti].c1ccc2c(c1)-c1nc-2nc2[nH]c(nc3nc(nc4[nH]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID136406513

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1118

Sulfuric acid

H2O4S

2 次

CONDITIONS

反应条件

温度: 5 °C

PROCEDURE

实验过程

Ten parts of the TiOPc crude prepared in Example 1 was gradually dissolved in 40 parts of 97% sulfuric acid at 2° C., and their mixture was stirred for 1 hour with maintaining its temperature at not higher than 5° C. Then, the resulting sulfuric acid solution was slowly poured into 400 parts of ice water with stirring at a high speed, and crystals precipitated were filtrated. The crystals were washed with distilled water until the acid did not remain, and then dried to give 9 parts of a titanium phthalocyanine compound. One part of this TiOPc was milled by a ball mill for 80 hours.

WORKUP

后处理

stirringwith stirring at a high speed, and crystals
customprecipitated
filtrationwere filtrated
washThe crystals were washed with distilled water until the acid
customdried

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b8180e8866a54b8fa58f042a52189166
来源数据集: uspto-grants-1989_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04882427
来源说明: uspto-grants-1989_11

反应 SMILES

[CH:1]1[CH:6]=[C:5]2[C:7]3[N-:40][C:39]([C:4]2=[CH:3][CH:2]=1)=[N:38][C:36]1=[N:37][C:29]([C:30]2[C:35]1=[CH:34][CH:33]=[CH:32][CH:31]=2)=[N:28][C:26]1=[N:27][C:19]([C:20]2[C:25]1=[CH:24][CH:23]=[CH:22][CH:21]=2)=[N:18][C:16]1[N-:17][C:9](=[C:10]2[C:15]=1[CH:14]=[CH:13][CH:12]=[CH:11]2)[N:8]=3.[O-2].[Ti+4:42]>S(=O)(=O)(O)O>[Ti:42].[CH:12]1[CH:13]=[CH:14][C:15]2[C:10](=[C:9]3[N:8]=[C:7]4[N:40]=[C:39]([C:4]5[CH:3]=[CH:2][CH:1]=[CH:6][C:5]=54)[N:38]=[C:36]4[NH:37][C:29]([C:30]5[CH:31]=[CH:32][CH:33]=[CH:34][C:35]=54)=[N:28][C:26]4=[N:27][C:19]([C:20]5[CH:21]=[CH:22][CH:23]=[CH:24][C:25]=54)=[N:18][C:16]=2[NH:17]3)[CH:11]=1