HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-(3-Phenoxyphenyl)ethanol → (R)alpha-methyl-3-phenoxy-benzyl (IR,cis) 2,2-dimethyl-3-[3-oxo-3-(2,2,2-trichloroethoxy)-1-propynyl]-cyclopropane-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-(3-Phenoxyphenyl)ethanol | HCID 12882419 | — |
| Reactant | (1R,cis)2,2-dimethyl-3-(2,2,2-trichloroethoxycarbonylethynyl)-cyclopropane-carboxylic acid | HCID 13093792 | — |
| Reactant | (R)alpha-methyl-3-phenoxy-benzyl (IR,cis) 2,2-dimethyl-3-[(Z) 3-oxo-3-(2-methoxyethoxy)-1-propenyl]-cyclopropane-carboxylate | HCID 70489338 | — |
| Product | (R)alpha-methyl-3-phenoxy-benzyl (IR,cis) 2,2-dimethyl-3-[3-oxo-3-(2,2,2-trichloroethoxy)-1-propynyl]-cyclopropane-carboxylate | HCID 53655047 | — |
Reaction Steps
Using the procedure of Step D of Example 9, 6 g of (IR,cis) 2,2-dimethyl-3-[3-oxo-3-(2,2,2-trichloroethoxy) -1-propynyl]-cyclopropane-carboxylic acid and 4.1 g of 1-(R) (3-phenoxy-phenyl)-ethanol were reacted to obtain after chromatography and elution with an 8-2 mixture of cyclohexane-ethyl acetate 4.38 g of (R)α-methoxy-3-phenoxy-benzyl (IR, cis) 2,2-dimethyl-3-[3-oxo-3-(2,2,2-trichloroethoxy)-1-propynyl]-cyclopropane-carboxylate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04883806 |
| Source dataset | uspto-grants-1989_11 |
| ORD ID | ord-775bca46d1234b2fb3fce41f78a61083 |
| Source note | uspto-grants-1989_11 |