4-Nitroaniline → HCID 136332750, compound

HRID 1643326Notes

Reaction equation

[N+:1]([C:4]1[CH:10]=[CH:9][C:7]([NH2:8])=[CH:6][CH:5]=1)([O-:3])=[O:2].[N:11]([O-])=O.[Na+].[CH3:15][C:16]1[CH:21]=[CH:20][C:19]([SH:22])=[CH:18][CH:17]=1>>[N+:1]([C:4]1[CH:10]=[CH:9][C:7]([N:8]=[N:11][C:18]2[CH:17]=[C:16]([CH3:15])[CH:21]=[CH:20][C:19]=2[SH:22])=[CH:6][CH:5]=1)([O-:3])=[O:2]

Participants

Reactant 3

HCID 74754-Nitroaniline

HCID 78114-Methylbenzenethiol

HCID 23668193Sodium Nitrite

Product 1

HCID 136332750HCID 136332750, compound

Procedure

This is prepared similarly to Example 1 using 19.6 g (142 mmoles) of 4-nitro-aniline, 10% sodium nitrite solution (103.5 ml), and 20 g (142 mmoles) of 4-methylthio-phenol.

Sources & evidence

ORD record: ord-171a11918c5448838e51db7e49dc2f0a
Source dataset: uspto-grants-2012_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08119778B2

Reaction notes

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