Aniline → HCID 136162363, compound

HRID 1643327Notes

Reaction equation

HRID 1643327 reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N:8]([O-])=O.[Na+].[CH2:12]([S:16][C:17]1[C:26]2[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=2)[C:20]([OH:27])=[CH:19][CH:18]=1)[CH2:13][CH2:14][CH3:15]>>[C:2]1([N:1]=[N:8][C:19]2[CH:18]=[C:17]([S:16][CH2:12][CH2:13][CH2:14][CH3:15])[C:26]3[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=3)[C:20]=2[OH:27])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 6115AnilineHCID 23668193Sodium NitriteHCID 66756967HCID 66756967, compound

Product 1

HCID 136162363HCID 136162363, compound

Procedure

This is prepared similarly to Example 1 using 0.8 g (8.6 mmoles) of aniline, 0.65 g (9.5 mmoles) of sodium nitrite, and 2 g (8.6 mmoles) of 4-butylthio-1-naphthol.

Sources & evidence

ORD record
ord-cadf94db3f2a4ff1a3174a8d956db87a
Source dataset
uspto-grants-2012_02
Patent number
US08119778B2

Reaction notes

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