4-Nitroaniline → HCID 136162367, compound

HRID 1643328Notes

Reaction equation

HRID 1643328 reaction equation
[N+:1]([C:4]1[CH:10]=[CH:9][C:7]([NH2:8])=[CH:6][CH:5]=1)([O-:3])=[O:2].[N:11]([O-])=O.[Na+].[CH2:15]([S:19][C:20]1[C:29]2[C:24](=[CH:25][CH:26]=[CH:27][CH:28]=2)[C:23]([OH:30])=[CH:22][CH:21]=1)[CH2:16][CH2:17][CH3:18]>>[N+:1]([C:4]1[CH:10]=[CH:9][C:7]([N:8]=[N:11][C:22]2[CH:21]=[C:20]([S:19][CH2:15][CH2:16][CH2:17][CH3:18])[C:29]3[C:24](=[CH:25][CH:26]=[CH:27][CH:28]=3)[C:23]=2[OH:30])=[CH:6][CH:5]=1)([O-:3])=[O:2]

Participants

4

Reactant 3

HCID 74754-NitroanilineHCID 23668193Sodium NitriteHCID 66756967HCID 66756967, compound

Product 1

HCID 136162367HCID 136162367, compound

Procedure

This is prepared similarly to Example 1 using 1.3 g (9.46 mmoles) of 4-nitro-aniline, 0.72 g (10.3 mmoles) of sodium nitrite, and 2 g (8.6 mmoles) of 4-butylthio-1-naphthol.

Sources & evidence

ORD record
ord-6b306a156e194e179a39b4cab34060d8
Source dataset
uspto-grants-2012_02
Patent number
US08119778B2

Reaction notes

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