Ethanol → Sodium ZINC monooctylphosphate

HRID 1645754Notes

Reaction equation

HRID 1645754 reaction equation
[CH2:1]([O:9][P:10](=[O:13])([OH:12])[OH:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].C(O)C.[OH-].[Na+:18].O.O.O.O.O.O.O.S([O-])([O-])(=O)=O.[Zn+2:31]>O>[CH2:1]([O:9][P:10]([O-:13])([O-:12])=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[Zn+2:31].[Na+:18]

Participants

6

Reactant 4

HCID 702EthanolHCID 14798Sodium Hydroxide2×HCID 19892Monooctyl phosphateHCID 62640Zinc Sulfate Heptahydrate

Product 1

HCID 19772871Sodium ZINC monooctylphosphate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

50 g of monooctylphosphoric acid and 100 g of ethanol were placed in a 500 ml reaction vessel. Further, a solution of 9.52 g of 96% sodium hydroxide (purity was taken into consideration by calculating it from the degree of neutralization determined by titration) dissolved in 200 g of ion-exchanged water was added thereto. After the temperature was elevated to 80° C., it was confirmed that they were dissolved. The solution was continuously stirred for 30 minutes. A solution of 34.2 g of zinc sulfate heptahydrate dissolved in 100 g of ion-exchanged water was added dropwise thereto. After the completion of the addition, the mixture was stirred for 30 minutes. 14.26 g of an aqueous solution of 33.33% sodium hydroxide was added dropwise thereto, to thereby adjust the pH of the reaction mixture to 5. Further, the mixture was stirred for one hour. After the completion of the reaction, the reaction mixture was cooled, and the product was collected by filtration, washed with water and dried to obtain 49.6 g of the particles of sodium zinc monooctylphosphate.

Workup

  1. additionwas added
  2. customwas elevated to 80° C.
  3. dissolutionwere dissolved
  4. additionwas added dropwise
  5. additionAfter the completion of the addition
  6. stirringthe mixture was stirred for 30 minutes
  7. stirringFurther, the mixture was stirred for one hour
  8. customAfter the completion of the reaction
  9. temperaturethe reaction mixture was cooled
  10. filtrationthe product was collected by filtration
  11. washwashed with water
  12. customdried

Sources & evidence

ORD record
ord-2f94a8d1741641058cc120eac2959b6e
Source dataset
uspto-grants-1993_01
Patent number
US05176904

Reaction notes

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