HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → HCID 19742105, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | (4'-Methyl[1,1'-biphenyl]-4-yl)(phenyl)methanone | HCID 11208026 | — |
| Catalyst | Dimethylcyanamide | HCID 15112 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | HCID 19742105 | HCID 19742105 | 89% |
Reaction Steps
A mixture of 26.1 g of 4-benzoyl-4'-methylbiphenyl, 18.6 g of N-bromosuccinimide and 0.18 g of azaisobutyronitrile in 600 mL of carbon tetrachloride was heated to boiling for 4 hours. The brown solution obtained was filtered and evaporated. The residue was recrystallized from cyclohexane. There are obtained 29.9 g (89%) of 4'-(bromomethyl)-4-biphenylyl phenyl ketone as colorless crystals with a m.p. of 110°-112° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05177067 |
| Source dataset | uspto-grants-1993_01 |
| ORD ID | ord-0d6a778e06e74990b180638270ffd191 |
| Source note | uspto-grants-1993_01 |