HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyl Sulfoxide → HCID 19801138, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyl Sulfoxide | HCID 679 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Oxalyl chloride | HCID 65578 | — |
| Reactant | HCID 19801151 | HCID 19801151 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 19801138 | HCID 19801138 | — |
Reaction Steps
The above alcohol (1 g) was oxidised under Swern conditions (dimethyl sulphoxide (450 mg), oxalyl chloride (248 μl), triethylamine (1.58 ml)) in dichloromethane (25 ml) to give 7-(3,5-bistrifluoromethylbenzyloxy)heptan-1al. This was used directly in the next stage.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05180737 |
| Source dataset | uspto-grants-1993_01 |
| ORD ID | ord-ffa27d90b557401e812ccff9e1d325c0 |
| Source note | uspto-grants-1993_01 |