Avarone → Avarol

HRID 1646626Notes

Reaction equation

HRID 1646626 reaction equation

[CH3:1][C@@H:2]1[C@:7]([CH2:9][C:10]2[C:16](=[O:17])[CH:15]=[CH:14][C:12](=[O:13])[CH:11]=2)([CH3:8])[C@@H:6]2[CH2:18][CH2:19][CH:20]=[C:21]([CH3:22])[C@@:5]2([CH3:23])[CH2:4][CH2:3]1>C(Cl)(Cl)Cl>[CH3:1][C@@H:2]1[C@:7]([CH2:9][C:10]2[CH:11]=[C:12]([OH:13])[CH:14]=[CH:15][C:16]=2[OH:17])([CH3:8])[C@@H:6]2[CH2:18][CH2:19][CH:20]=[C:21]([CH3:22])[C@@:5]2([CH3:23])[CH2:4][CH2:3]1

Participants

3

Reactant 1

HCID 72186Avarone

Product 1

HCID 72185Avarol

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Whitish crystals; m.p. 146°-148° C. (chloroform); other characteristics same as for Avarone.

Sources & evidence

ORD record: ord-4845eb33d1bf4110a9751f95c1d99124
Source dataset: uspto-grants-1993_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05180748

Reaction notes

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