HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Chloro-2-nitro-1-(phenylthio)benzene → 5-Chloro-2-phenylsulfanyl-phenylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Chloro-2-nitro-1-(phenylthio)benzene | HCID 376977 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 5-Chloro-2-phenylsulfanyl-phenylamine | HCID 2063717 | — |
Reaction Steps
An ethanol solution of 1.0 g (4.2 mmol) of 4-chloro-2-nitro-1-(phenylthio)benzene (32), prepared in the manner described above in Example 32, is shaken in a Parr hydrogenator at 30 psi hydrogen with Raney nickel at room temperature for 3 hours. The catalyst is filtered from the reaction, and the solution is concentrated under vacuum.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05182272 |
| Source dataset | uspto-grants-1993_01 |
| ORD ID | ord-b24d7ee1519a44519476e96d15eba075 |
| Source note | uspto-grants-1993_01 |