Ammonia → HCID 19921107, compound

HRID 1647894Notes

Reaction equation

HRID 1647894 reaction equation
[C:1]([C:3]1[CH:8]=[CH:7][C:6]([C:9]2[N:13]([CH2:14][CH2:15][C:16]3[CH:21]=[CH:20][C:19](OC)=[C:18](OC)[CH:17]=3)[C:12]3[CH:26]=[CH:27][C:28]([C:30]([NH:32][CH2:33][CH2:34][C:35]([O:37][CH3:38])=[O:36])=[O:31])=[CH:29][C:11]=3[N:10]=2)=[CH:5][CH:4]=1)#[N:2].N>C(OCC)(=O)C.C(O)C>[C:1]([C:3]1[CH:4]=[CH:5][C:6]([C:9]2[N:13]([CH2:14][CH2:15][CH2:16][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:7][CH2:8][CH2:3][CH2:4][CH2:5][CH3:6])[C:12]3[CH:26]=[CH:27][C:28]([C:30]([NH:32][CH2:33][CH2:34][C:35]([O:37][CH3:38])=[O:36])=[O:31])=[CH:29][C:11]=3[N:10]=2)=[CH:7][CH:8]=1)#[N:2]

Participants

4

Reactant 2

HCID 222AmmoniaHCID 19921473HCID 19921473, compound

Product 1

HCID 19921107HCID 19921107, compound

Reagents, catalysts & solvents 1

HCID 21584252Ethanol ethylacetateSolvent

Procedure

The same procedure is used as in (1) Rf value: 0.60 (silica gel; ethyl acetate/ethanol/conc. ammonia=50:2:0.02)

Sources & evidence

ORD record
ord-fdc7d3811c374463a33274bab05eace9
Source dataset
uspto-grants-1995_07
Patent number
US05434150

Reaction notes

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