1,8-Dibromooctane → HCID 54052169, compound

HRID 1648020Notes

Reaction equation

HRID 1648020 reaction equation
[CH2:1]([O:3][C:4](=[O:27])[CH2:5][CH2:6][C:7]1[CH:12]=[C:11]([C:13]([C:15]2[CH:20]=[CH:19][CH:18]=[C:17]([C:21]([O:23][CH2:24][CH3:25])=[O:22])[CH:16]=2)=[O:14])[CH:10]=[CH:9][C:8]=1[OH:26])[CH3:2].[Br:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36]Br>>[CH2:1]([O:3][C:4](=[O:27])[CH2:5][CH2:6][C:7]1[CH:12]=[C:11]([C:13]([C:15]2[CH:20]=[CH:19][CH:18]=[C:17]([C:21]([O:23][CH2:24][CH3:25])=[O:22])[CH:16]=2)=[O:14])[CH:10]=[CH:9][C:8]=1[O:26][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][Br:28])[CH3:2]

Participants

3

Reactant 2

HCID 783101,8-DibromooctaneHCID 147396575-[3-(Ethoxycarbonyl)benzoyl]-2-hydroxybenzenepropanoic acid ethyl ester

Product 1

HCID 54052169HCID 54052169, compoundYield 72.6%

Procedure

Starting with 0.370 g (1.0 mmol) of 5-[[3-(ethoxycarbonyl)phenyl]carbonyl]-2-hydroxybenzenepropanoic acid ethyl ester, and 2.17 g (7.98 mmol) of 1,8-dibromooctane, the title compound was obtained as a colorless oil, in 72.6% yield, using the procedure of example 21.

Sources & evidence

ORD record
ord-aef99c14219a40e88f436bb06dca966d
Source dataset
uspto-grants-1995_07
Patent number
US05434186

Reaction notes

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