Acetic Acid Mixture with Hydrobromic Acid → HCID 70453019, compound

HRID 1648778Notes

Reaction equation

HRID 1648778 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH3:8])=[C:4]([O:9][C:10]2[CH:15]=[CH:14][C:13]([O:16]C)=[CH:12][CH:11]=2)[CH:3]=1.Br.C(O)(=O)C>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH3:8])=[C:4]([O:9][C:10]2[CH:15]=[CH:14][C:13]([OH:16])=[CH:12][CH:11]=2)[CH:3]=1

Participants

3

Reactant 2

HCID 21893785Acetic Acid Mixture with Hydrobromic AcidHCID 70453018HCID 70453018, compound

Product 1

HCID 70453019HCID 70453019, compound

Procedure

4-chloro-o-cresol and 4-bromoanisole yield p-(p-chloro-o-tolyloxy)anisole of b.p. 112°-116° C./0.04 Torr and reaction with hydrobromic acid/acetic acid yields p-(p-chloro-o-tolyloxy)phenol; m.p. 83°-85° C.;

Sources & evidence

ORD record
ord-a1cbd51d2e814cf8846b27a4643734db
Source dataset
uspto-grants-1983_11
Patent number
US04413010

Reaction notes

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